An open hollow polyoxovanadate cage based on {Nb(V5)} pentagons with size-selective encapsulation properties

Renbo Fang; Di Zhang; Jing Dong; Yeqin Feng; Chengpeng Liu; Liaoyuan Yao; Yingnan Chi; Changwen Hu

doi:10.1039/d5cc01376c

An open hollow polyoxovanadate cage based on {Nb(V₅)} pentagons with size-selective encapsulation properties

Renbo Fang
, Di Zhang
, Jing Dong^*
, Yeqin Feng
, Chengpeng Liu
, Liaoyuan Yao
, Yingnan Chi^*
, Changwen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Beijing Technology and Business University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

An open hollow polyoxovanadate (POV) cage, V14Nb2P8, has been successfully constructed using {Nb(V₅)} pentagons as building blocks. The POV cage features a crown-ether-like {V₄P₄O₈} opening that can selectively coordinate with Cs⁺ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.

Original language	English
Pages (from-to)	6182-6185
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	33
DOIs	https://doi.org/10.1039/d5cc01376c
Publication status	Published - 25 Mar 2025

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10.1039/d5cc01376c

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title = "An open hollow polyoxovanadate cage based on \{Nb(V5)\} pentagons with size-selective encapsulation properties",

abstract = "An open hollow polyoxovanadate (POV) cage, V14Nb2P8, has been successfully constructed using \{Nb(V5)\} pentagons as building blocks. The POV cage features a crown-ether-like \{V4P4O8\} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.",

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AU - Fang, Renbo

AU - Zhang, Di

AU - Dong, Jing

AU - Feng, Yeqin

AU - Liu, Chengpeng

AU - Yao, Liaoyuan

AU - Chi, Yingnan

AU - Hu, Changwen

PY - 2025/3/25

Y1 - 2025/3/25

N2 - An open hollow polyoxovanadate (POV) cage, V14Nb2P8, has been successfully constructed using {Nb(V5)} pentagons as building blocks. The POV cage features a crown-ether-like {V4P4O8} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.

AB - An open hollow polyoxovanadate (POV) cage, V14Nb2P8, has been successfully constructed using {Nb(V5)} pentagons as building blocks. The POV cage features a crown-ether-like {V4P4O8} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.

UR - https://www.scopus.com/pages/publications/105001686385

U2 - 10.1039/d5cc01376c

DO - 10.1039/d5cc01376c

M3 - Article

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AN - SCOPUS:105001686385

SN - 1359-7345

VL - 61

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EP - 6185

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

An open hollow polyoxovanadate cage based on {Nb(V₅)} pentagons with size-selective encapsulation properties

Abstract

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